Issue 57, 2012
From the journal:

Chemical Communications

Versatile gold catalyzed transglycosidation at ambient temperature†

Abhijeet K. Kayasthaa  and  Srinivas Hotha*a  

* Corresponding authors

a Department of Chemistry, Indian Institute of Science Education & Research, Pune, India
E-mail: s.hotha@iiserpune.ac.in
Fax: +91 20 2589 9790
Tel: +91 20 2590 8015

Abstract

Glycosidation with stable alkyl glycosyl donors using a catalytic amount of gold salts is promising. Herein, 1-ethynylcyclohexanyl glycosides are identified as novel donors at room temperature and mechanistic investigation showed that the leaving group simply extrudes out.

Graphical abstract: Versatile gold catalyzed transglycosidation at ambient temperature

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Article information

DOI
https://doi.org/10.1039/C2CC32649C
Article type
Communication
Submitted
14 Apr 2012
Accepted
18 May 2012
First published
18 May 2012

Chem. Commun., 2012,48, 7161-7163

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Versatile gold catalyzed transglycosidation at ambient temperature

A. K. Kayastha and S. Hotha, Chem. Commun., 2012, 48, 7161 DOI: 10.1039/C2CC32649C

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