Highly selective reactions of C60Cl6 with thiols for the synthesis of functionalized [60]fullerene derivatives

Ekaterina A. Khakina; Anastasiya A. Yurkova; Alexander S. Peregudov; Sergey I. Troyanov; Vyacheslav V. Trush; Andrey I. Vovk; Alexander V. Mumyatov; Vyacheslav M. Martynenko; Jan Balzarini; Pavel A. Troshin

doi:10.1039/C2CC32517A

Highly selective reactions of C₆₀Cl₆ with thiols for the synthesis of functionalized [60]fullerene derivatives†

Ekaterina A. Khakina,^a Anastasiya A. Yurkova,^a Alexander S. Peregudov,^b Sergey I. Troyanov,^c Vyacheslav V. Trush,^d Andrey I. Vovk,^d Alexander V. Mumyatov,^a Vyacheslav M. Martynenko,^a Jan Balzarini^e and Pavel A. Troshin*^a

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^a IPCP RAS, Semenov Prospect 1, Chernogolovka, Russia
E-mail: troshin2003@inbox.ru
Fax: +7 496522-3507
Tel: +7 496522 1418

^b INEOS RAS, Vavylova St. 28, B-334, Moscow, Russia

^c Department of Chemistry, Moscow State University, Moscow, Leninskie gory, Russia

^d Institute of Bioorganic Chemistry and Petrochemistry, National Academy of Sciences of Ukraine, Murmanska, 1, 02660 Kyiv-94, Ukraine

^e Rega Institute for Medical Research, Minderbroedersstraat 10, B-3000, Leuven, Belgium

Abstract

Chlorofullerene C₆₀Cl₆ undergoes highly selective reactions with thiols forming compounds C₆₀[SR]₅H with high yields. These reactions open up straightforward synthetic routes to many functionalized fullerene derivatives, e.g. water-soluble compounds showing interesting biological activities.

Chemical Communications

Highly selective reactions of C₆₀Cl₆ with thiols for the synthesis of functionalized [60]fullerene derivatives†

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Highly selective reactions of C₆₀Cl₆ with thiols for the synthesis of functionalized [60]fullerene derivatives

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