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Abstract | Cited by

We report the first, general and selective acylation of the least reactive hydroxyl group among six secondary hydroxyl groups of inositol in high yield, using very cheap and easy-to-make H2SO4–silica as the catalyst, providing easy access to bioactive molecules.

Graphical abstract: Regioselectivity among six secondary hydroxyl groups: selective acylation of the least reactive hydroxyl groups of inositol

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