Issue 18, 2012
From the journal:

Chemical Communications

Fibre optic ATR-IR spectroscopy at cryogenic temperatures: in-line reaction monitoring on organolithium compounds†

Daniel Lumpi,*a   Christoph Wagner,b   Matthias Schöpf,a   Ernst Horkel,a   Georg Ramer,b   Bernhard Lendlb  and  Johannes Fröhlich*a  

* Corresponding authors

a Institute of Applied Synthetic Chemistry, Vienna University of Technology, Getreidemarkt 9/163-OC, 1060 Wien, Austria
E-mail: daniel.lumpi@tuwien.ac.at, johannes.froehlich@tuwien.ac.at
Fax: +43 1 58801 154 99
Tel: +43 1 58801 163 719

b Institute of Chemical Technologies and Analytics, Vienna University of Technology, Getreidemarkt 9/164-AC, 1060 Wien, Austria

Abstract

A reliable methodology, utilising an ATR-IR fibre probe, for in-line monitoring of low temperature reactions is presented. The application of this convenient set-up enables a fast and safe exploration of highly reactive substrates. Hence, in situ monitoring of lithiation reactions is realised and the potential to investigate sensitive intermediates is being demonstrated.

Graphical abstract: Fibre optic ATR-IR spectroscopy at cryogenic temperatures: in-line reaction monitoring on organolithium compounds

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Article information

DOI
https://doi.org/10.1039/C2CC16016A
Article type
Communication
Submitted
27 Sep 2011
Accepted
06 Jan 2012
First published
25 Jan 2012

Chem. Commun., 2012,48, 2451-2453

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Fibre optic ATR-IR spectroscopy at cryogenic temperatures: in-line reaction monitoring on organolithium compounds

D. Lumpi, C. Wagner, M. Schöpf, E. Horkel, G. Ramer, B. Lendl and J. Fröhlich, Chem. Commun., 2012, 48, 2451 DOI: 10.1039/C2CC16016A

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