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Issue 24, 2012
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Twist angle perturbation on mixed (phthalocyaninato)(porphyrinato) dysprosium(iii) double-decker SMMs

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Abstract

Correlation between molecular structures and slow relaxation of magnetization of three mixed (phthalocyaninato)(porphyrinato) dysprosium(III) double-deckers clearly reveals the effect of the sandwich-type molecular structure, in particular the twist angle, on the quantum tunneling (QT) at zero dc field of these complexes, providing the first direct evidence to the theoretical inference.

Graphical abstract: Twist angle perturbation on mixed (phthalocyaninato)(porphyrinato) dysprosium(iii) double-decker SMMs

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Article information


Submitted
21 Oct 2011
Accepted
17 Jan 2012
First published
18 Jan 2012

Chem. Commun., 2012,48, 2973-2975
Article type
Communication

Twist angle perturbation on mixed (phthalocyaninato)(porphyrinato) dysprosium(III) double-decker SMMs

H. Wang, K. Wang, J. Tao and J. Jiang, Chem. Commun., 2012, 48, 2973
DOI: 10.1039/C2CC16543K

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