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Issue 23, 2010
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A butenolide intermediate in methylenomycin furanbiosynthesis is implied by incorporation of stereospecifically 13C-labelled glycerols

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Abstract

The label from [3-13C]-L-glycerol is incorporated into the hydroxymethyl group of methylenomycin furans suggesting a butenolide intermediate in their biosynthesis.

Graphical abstract: A butenolide intermediate in methylenomycin furan biosynthesis is implied by incorporation of stereospecifically 13C-labelled glycerols

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Publication details

The article was received on 08 Jan 2010, accepted on 19 Mar 2010 and first published on 01 Apr 2010


Article type: Communication
DOI: 10.1039/C000496K
Chem. Commun., 2010,46, 4079-4081

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    A butenolide intermediate in methylenomycin furan biosynthesis is implied by incorporation of stereospecifically 13C-labelled glycerols

    C. Corre, S. W. Haynes, N. Malet, L. Song and G. L. Challis, Chem. Commun., 2010, 46, 4079
    DOI: 10.1039/C000496K

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