Issue 23, 2010
From the journal:

Chemical Communications

Synthesis of reaction-ready 6,6′-biindole and 6,6′-biisatinviapalladium(ii)-catalysed intramolecular C–H functionalisation†

Allan B. Gamblea  and  Paul A. Keller*a  

* Corresponding authors

a School of Chemistry, University of Wollongong, Wollongong, Australia
E-mail: keller@uow.edu.au
Fax: +61 2 4221 4287
Tel: +61 2 4221 4692

Abstract

The first synthesis of a 6,6′-biindole and 6,6′-biisatin scaffold is reported with the penultimate step being the formation of the di-heterocyclic ring by Pd(II)-catalysed intramolecular C–H functionalisation and Sandmeyer cyclisation, respectively.

Graphical abstract: Synthesis of reaction-ready 6,6′-biindole and 6,6′-biisatin via palladium(ii)-catalysed intramolecular C–H functionalisation

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Article information

DOI
https://doi.org/10.1039/C002098B
Article type
Communication
Submitted
01 Feb 2010
Accepted
04 Mar 2010
First published
23 Mar 2010

Chem. Commun., 2010,46, 4076-4078

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Synthesis of reaction-ready 6,6′-biindole and 6,6′-biisatin via palladium(II)-catalysed intramolecular C–H functionalisation

A. B. Gamble and P. A. Keller, Chem. Commun., 2010, 46, 4076 DOI: 10.1039/C002098B

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