Issue 19, 2005
From the journal:

Dalton Transactions

A new structural form for a decanuclear copper(ii) assembly†

Vadapalli Chandrasekhar,*a   Loganathan Nagarajan,a   Kandasamy Gopal,a   Viswanathan Baskara  and  Paul Kögerlerb  

* Corresponding authors

a Department of Chemistry, Indian Institute of Technology, Kanpur, India
E-mail: vc@iitk.ac.in
Fax: (+91) 512 259 0007/7436
Tel: (+91) 512 259 7259

b Ames Laboratory, Department of Physics and Astronomy, Iowa State University, Ames, Iowa, USA

Abstract

The synthesis and structure of a novel decanuclear copper(II) cage is reported. The assembly of the cage is facilitated by the cumulative coordinative interaction of tert-butyl phosphonate, 2-pyridylpyrazole and hydroxide ligands with copper(II) ions. Magnetic studies of this decanuclear copper(II) cage indicate complex antiferromagnetic behaviour.

Graphical abstract: A new structural form for a decanuclear copper(ii) assembly

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Article information

DOI
https://doi.org/10.1039/B510145J
Article type
Communication
Submitted
18 Jul 2005
Accepted
09 Aug 2005
First published
22 Aug 2005

Dalton Trans., 2005, 3143-3145

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A new structural form for a decanuclear copper(II) assembly

V. Chandrasekhar, L. Nagarajan, K. Gopal, V. Baskar and P. Kögerler, Dalton Trans., 2005, 3143 DOI: 10.1039/B510145J

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