Structure and photoluminescence property of two-dimensional coordination polymer complexes involving CuI6X6				(X = Cl, Br, I) hexagon prism cluster supported by a tripodal tripyridine ligand with 1,3,5-triethylbenzene spacer

Hiromi Ohi; Yoshimitsu Tachi; Takashi Kunimoto; Shinobu Itoh

doi:10.1039/B508747C

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Structure and photoluminescence property of two-dimensional coordination polymer complexes involving Cu^I₆X₆ (X = Cl, Br, I) hexagon prism cluster supported by a tripodal tripyridine ligand with 1,3,5-triethylbenzene spacer†

Hiromi Ohi,^a Yoshimitsu Tachi,^a Takashi Kunimoto^b and Shinobu Itoh*^a

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* Corresponding authors

^a Department of Chemistry, Graduate School of Science, Osaka City University, 3-3-138 Sugimoto, Sumiyoshi-ku, Osaka 558-8585, Japan
E-mail: shinobu@sci.osaka-cu.ac.jp
Fax: +81-6-6605-2564
Tel: +81-6-6605-2564

^b Department of Nano and Bio Material Engineering, Tokushima Bunri University, Shido, Sanuki-city, Kagawa 769-2193, Japan
E-mail: kunimoto@febunri-u.ac.jp
Fax: +81-87-894-4201
Tel: +81-87-894-5111 (Ex. 3426)

Abstract

Treatment of cuprous halide (Cu^IX, X = Cl, Br, and I) and a tripodal tripyridine ligand (L) consisting of a 1,3,5-triethylbenzene spacer gave a unique two-dimensional (2D) polymer sheet structure involving a rare Cu^I₆X₆ hexagon prism cluster unit, which exhibits intense fluorescence around 448–476 nm.

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Article information

DOI: https://doi.org/10.1039/B508747C
Article type: Communication
Submitted: 22 Jun 2005
Accepted: 17 Aug 2005
First published: 26 Aug 2005

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Dalton Trans., 2005, 3146-3147

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Structure and photoluminescence property of two-dimensional coordination polymer complexes involving Cu^I₆X₆ (X = Cl, Br, I) hexagon prism cluster supported by a tripodal tripyridine ligand with 1,3,5-triethylbenzene spacer

H. Ohi, Y. Tachi, T. Kunimoto and S. Itoh, Dalton Trans., 2005, 3146 DOI: 10.1039/B508747C

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Dalton Transactions