Issue 11, 2003
From the journal:

Chemical Communications

Cooperative thermal and optical switching of spin states in a new two-dimensional coordination polymer

Virginie Niel,a   Ana Galet,ab   Ana B. Gaspar,a   M. Carmen Muñozb  and  José A. Real*a  

* Corresponding authors

a Institut de Ciencia Molecular/Departament de Química Inorgánica, Universitat de València, Doctor Moliner 50, Burjassot, Spain
E-mail: jose.a.real@uv.es

b Departament de Física Aplicada, Universitat Politècnica de València, Camino de Vera s/n, 46071, Valencia, Spain

Abstract

{Fe(pmd)2[Cu(CN)2]2} (pmd = pyrimidine) displays a rigid two-dimensional structure and undergoes thermal- and optical-driven spin crossover behaviour; cooperative elastic coupling between iron(II) ions in the framework induces thermal hysteresis in the HS ↔ LS conversion and sigmoidal HS → LS relaxation of the photo-induced HS state at low temperatures.

Graphical abstract: Cooperative thermal and optical switching of spin states in a new two-dimensional coordination polymer

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Article information

DOI
https://doi.org/10.1039/B301806G
Article type
Communication
Submitted
14 Feb 2003
Accepted
02 Apr 2003
First published
23 Apr 2003

Chem. Commun., 2003, 1248-1249

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Cooperative thermal and optical switching of spin states in a new two-dimensional coordination polymer

V. Niel, A. Galet, A. B. Gaspar, M. C. Muñoz and J. A. Real, Chem. Commun., 2003, 1248 DOI: 10.1039/B301806G

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