Issue 11, 2003
From the journal:

Chemical Communications

Radical anion chain process initiated by a dissociative electron transfer to a monocyclic endoperoxide.

Donald L. B. Stringle,a   R. Nevin Campbella  and  Mark S. Workentin*a  

* Corresponding authors

a Department of Chemistry, The University of Western Ontario, London, ON, Canada
E-mail: mworkent@uwo.ca
Fax: 519 661 3022
Tel: 519 661 2111 Ext 86319

Abstract

Electron transfer to 3,3,6,6-tetraphenyl-1,2-dioxane results in the cleavage of the oxygen-oxygen bond, generating a distonic radical anion intermediate whose fragmentation initiates an unprecedented radical anion chain process in competition with a second electron transfer.

Graphical abstract: Radical anion chain process initiated by a dissociative electron transfer to a monocyclic endoperoxide.

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Article information

DOI
https://doi.org/10.1039/B301909H
Article type
Communication
Submitted
17 Feb 2003
Accepted
13 Mar 2003
First published
23 Apr 2003

Chem. Commun., 2003, 1246-1247

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Radical anion chain process initiated by a dissociative electron transfer to a monocyclic endoperoxide.

D. L. B. Stringle, R. Nevin Campbell and M. S. Workentin, Chem. Commun., 2003, 1246 DOI: 10.1039/B301909H

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