The synthetic octapeptide lophyrotomin (PhCO-D-Ala-D-Phe-L-Val-L-lle-D-Asp-L-Asp-D-Glu-L-Gln), the toxic factor of the larvae of an Australian species of sawfly, Lophyrotoma interrupta, has been prepared by solid-phase synthesis and proved to be identical with the natural material.
F. De Angelis, A. Scaloni, V. Caciagli and A. S. Verdini, J. Chem. Soc., Chem. Commun., 1994, 445 DOI: 10.1039/C39940000445
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