The 3d electrons of chromium(III) and the unpaired electron of the nitroxide radical interact ferro- and antiferro-magnetically in chloro-meso-tetraphenylporphyrinatochromium(III) ligated with 3- and 4-(N-oxy-N-tert-butylamino)pyridines to produce quintet and triplet ground states, respectively.
M. Kitano, N. Koga and H. Iwamura, J. Chem. Soc., Chem. Commun., 1994, 447 DOI: 10.1039/C39940000447
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