Addition of an alkyl substituted triaminopyrimidine, TAP, to a solution of porphyrin 2 bearing two rigidly attached complementary hydrogen bonding moieties of the uracil type, leads to the self-assembly of a bisporphyrin supramolecular cage structure 1 from the syn rotamer and probably a zig-zag strand from the anti rotamer.
C. M. Drain, R. Fischer, E. G. Nolen and J. Lehn, J. Chem. Soc., Chem. Commun., 1993, 243 DOI: 10.1039/C39930000243
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