By using photocurrent spectroscopy it is shown that the first traces of poly(3-methylthiophene) electropolymerized onto bare indium tin oxide (ITO) already have a long conjugation length, whereas electropolymerization onto ITO with immobilized bithiophene or bare platinum results in a stepwise chain growth of the surface-confined polymer.
J. Kankare, V. Vuorinen, M. Alanko and J. Lukkari, J. Chem. Soc., Chem. Commun., 1993, 241 DOI: 10.1039/C39930000241
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