The elimination of thiocyanic acid from the stereoisomers of the hex-3-ene-2,5-diyl dithiocyanates, 4a, 4b, 6a and 6b, in the presence of a strong neutral base in an organic solvent, yields mixtures of the hex-2,4-dien-2-yl thiocyanates 9, 10 and 11via a preferentially syn process.
J. Schoepfer, E. Eichenberger and R. Neier, J. Chem. Soc., Chem. Commun., 1993, 246 DOI: 10.1039/C39930000246
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