Dioxomolybdenum(VI) complexes including MoO2(dipic)(HMPA)2a and MoO2(dedtc)22b(dipic = 2,6-pyridinedicarboxylate; HMPA = hexamethylphosphoramide; dedtc =N,N-diethyl dithiocarbamate) catalyse the allylic amination of alkenes by phenyl hydroxylamine; the reactions are characterized by a high degree of regioselectivity resulting from double bond migration.
A. Srivastava, Y. Ma, R. Pankayatselvan, W. Dinges and K. M. Nicholas, J. Chem. Soc., Chem. Commun., 1992, 853 DOI: 10.1039/C39920000853
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