p-tert-Butylcalix[8]arene interacts with cryptands 22 and 222 in benzonitrile to give 1 : 1 electrolytes, and thermodynamic, electrochemical and structural aspects of this interaction are reported for the first time; the results suggest that cryptand 222 hosts a proton from the calixarene in its cavity.
A. F. D. de Namor, M. T. G. Pardo, L. Muñoz, D. A. P. Tanaka, F. J. S. Velarde and M. C. Cabaleiro, J. Chem. Soc., Chem. Commun., 1992, 855 DOI: 10.1039/C39920000855
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