Nearly all the substances generated in water and said to involve rhodium-(IV), -(V) and -(VI) species, such as ‘Claus’ blue, ‘are in fact superoxides of rhodium(III); the superoxide ligand in Claus’ blue results from oxidation of hydroxide by dichlorine.
I. J. Ellison and R. D. Gillard, J. Chem. Soc., Chem. Commun., 1992, 851 DOI: 10.1039/C39920000851
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