Issue 18, 1991

C–H ⋯ O hydrogen bonding and topochemistry in crystalline 3,5-dinitrocinnamic acid and its 1 : 1 donor–acceptor complex with 2,5-dimethoxycinnamic acid

Abstract

3,5-Dinitrocinnamic acid adopts an unusual crystal structure wherein C–H ⋯ O hydrogen bonds dictate the symmetry of the O–H ⋯ O network while its 1 : 1 molecular complex with 2, 5-dimethoxycinnamic acid is photoreactive in the solid state to yield an unsymmetrical cyclobutane dimer.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1991, 1239-1241

C–H ⋯ O hydrogen bonding and topochemistry in crystalline 3,5-dinitrocinnamic acid and its 1 : 1 donor–acceptor complex with 2,5-dimethoxycinnamic acid

G. R. Desiraju and C. V. K. M. Sharma, J. Chem. Soc., Chem. Commun., 1991, 1239 DOI: 10.1039/C39910001239

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