The total synthesis of (–)-indolizidines 205A and 235B, alkaloids from the arrow poison-frog, via a common chiral oxazino-lactam, prepared by an asymmetric intramolecular Diels–Alder reaction of an N-acylnitroso intermediate, is described.
Y. Shishido and C. Kibayashi, J. Chem. Soc., Chem. Commun., 1991, 1237 DOI: 10.1039/C39910001237
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