Issue 19, 1987
From the journal:

Journal of the Chemical Society, Chemical Communications

Preparation of the titanium bisthionylimide complex [Cp2Ti(NSO)2] and the silyl sulphur di-imide derivative [Cp2Ti(NSNSiMe3)2]: precursors of novel metallacycles. Crystal structure of the thionylimide (Cp =η5-C5H5)

Herbert Plenio,   Herbert W. Roesky,   Mathias Noltemeyer  and  George M. Sheldrick  

Abstract

The bisthionylimide complex [Cp2Ti(NSO)2](Cp =η5-C5H5) was prepared by reaction of [Cp2TiCl2] and KNSO and its X-ray crystal structure determined; reaction of this compound with LiN(SiMe3)2 yielded [Cp2Ti(NSNSiMe3)2].

About
Cited by
Related
Download options Please wait...

Article information

DOI
https://doi.org/10.1039/C39870001483
Article type
Paper

J. Chem. Soc., Chem. Commun., 1987, 1483-1484

Permissions

Request permissions

Preparation of the titanium bisthionylimide complex [Cp2Ti(NSO)2] and the silyl sulphur di-imide derivative [Cp2Ti(NSNSiMe3)2]: precursors of novel metallacycles. Crystal structure of the thionylimide (Cp =η5-C5H5)

H. Plenio, H. W. Roesky, M. Noltemeyer and G. M. Sheldrick, J. Chem. Soc., Chem. Commun., 1987, 1483 DOI: 10.1039/C39870001483

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Spotlight

Advertisements