The synthesis and c.d. spectra of optically active cobalt(III)-tren [tren = tris(2-aminoethyl)amine] complexes of a β-diketone are described; the chirality of the complexes arises from restricted rotation of the aryl group.
Y. Nakano, Y. Yoshikawa, J. Hasegawa, T. Asano, Y. Igarashi and S. Masuhara, J. Chem. Soc., Chem. Commun., 1987, 1481 DOI: 10.1039/C39870001481
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