Issue 19, 1987
From the journal:

Journal of the Chemical Society, Chemical Communications

C-H rather than O–H activation: synthesis and molecular structure of a cationic cis-hydrido-σ-acetylide complex of rhodium

Todd B. Marder,   David Zargarian,   Joseph C. Calabrese,   Thomas H. Herskovitz  and  David Milstein  

Abstract

Terminal alkynes, including those with acidic O–H groups, react with [Rh(PMe3)4]Cl in tetrahydrofuran (THF) or in water yielding cis-hydrido-σ-acetylide complexes via C-H activation; the molecular structure of cis-[Rh(PMe3)4(H)(C[triple bond, length half m-dash]C–CH2OH)]Cl has been determined by X-ray diffraction.

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Article information

DOI
https://doi.org/10.1039/C39870001484
Article type
Paper

J. Chem. Soc., Chem. Commun., 1987, 1484-1485

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C-H rather than O–H activation: synthesis and molecular structure of a cationic cis-hydrido-σ-acetylide complex of rhodium

T. B. Marder, D. Zargarian, J. C. Calabrese, T. H. Herskovitz and D. Milstein, J. Chem. Soc., Chem. Commun., 1987, 1484 DOI: 10.1039/C39870001484

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