Isoquinolines (3) and (5) are formed under miled neutral conditions by intramolecular aza-Wittig reactions of iminophospranes, readily derived from azides (1) and (4) with trithyl phosphite, the azafluranthene (7) can also be prepared from the isolable iminophosphoranes (8), (9), and (10).
D. M. B. Hickey, A. R. MacKenzie, C. J. Moody and C. W. Ress, J. Chem. Soc., Chem. Commun., 1984, 776 DOI: 10.1039/C39840000776
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