SCHEDULED MAINTENANCE
The action of lithium metal on tetrakis(dimethylbromisilyl)silane or tetrakis(dimethylchlorosilyl)silane in tetrahydrofuran produces the first spiropentasilane, a higly strained polysilane that undergoes efficient cleavage reactions with lithium aluminium hydride, methylmagnesium bromide and phosphorus pentachloride.
P. Boudjouk and R. Sooriyakumaran, J. Chem. Soc., Chem. Commun., 1984, 777 DOI: 10.1039/C39840000777
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