Issue 21, 1981

Evidence for secondary building unit effects on the solid state 29Si n.m.r. resonance of silicon in zeolitic structures

Abstract

Zeolites which contain five-membered rings of silica tetrahedra (HZ mordenite, Na-ZSM-5, and H-ZSM-11) present a 29Si-n.m.r. line at ca.–113 p.p.m. in contrast with other zeolites which do not contain this building unit (Na-A, Na-X, Na-Y, and H-L), for which resonance occurs in the –80 to –106 p.p.m. range, depending on the Si:Al ratio.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1981, 1129-1131

Evidence for secondary building unit effects on the solid state 29Si n.m.r. resonance of silicon in zeolitic structures

J. B. Nagy, J. Gilson and E. G. Derouane, J. Chem. Soc., Chem. Commun., 1981, 1129 DOI: 10.1039/C39810001129

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