Issue 21, 1981

Cycloadditions of nitrile oxides to compounds containing two-co-ordinate phosphorus or arsenic. Kinetic and thermodynamic regioselectivity

Abstract

Cycloaddition of p-chlorobenzonitrile oxide takes place only at the C[double bond, length as m-dash]P bond of the diazaphosphole (1) yielding one regioisomer (3), and at the C[double bond, length as m-dash]As bond of the diaza-arsole (4) yielding the analogous regioisomer (5) as the kinetic product, the other regioisomer (6) being the thermodynamic product.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1981, 1131-1132

Cycloadditions of nitrile oxides to compounds containing two-co-ordinate phosphorus or arsenic. Kinetic and thermodynamic regioselectivity

R. Carrié, Y. Y. C. Y. L. Ko, F. De Sarlo and A. Brandi, J. Chem. Soc., Chem. Commun., 1981, 1131 DOI: 10.1039/C39810001131

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Spotlight

Advertisements