Issue 21, 1981

Stereoselective adsorption on a clay surface modified by an optically active nickel(II) tris(1,10-phenanthroline) chelate

Abstract

Adsorption of the optically active (+)510[Fe(phen)3]2+(phen = 1, 10-phenanthroline) on a coloidal clay surface proceeds more rapidly when the surface is already occupied by the corresponding nickel chelate with the opposite chirality, (–)546[Ni(phen)3]2+, than when it is occupied by the different enantiomer, (+)546[Ni(phen)3]2+.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1981, 1128-1129

Stereoselective adsorption on a clay surface modified by an optically active nickel(II) tris(1,10-phenanthroline) chelate

A. Yamagishi, J. Chem. Soc., Chem. Commun., 1981, 1128 DOI: 10.1039/C39810001128

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