SCHEDULED MAINTENANCE
Reaction of MoCl5 with 2-mercaptoethyl sulphide, (HSCH2CH2)2S, (mes), yields a MoIV complex [Mo(mes)2], which possesses trigonal prismatic geometry through co-ordination to both mercapto- and sulphide-sulphur donors; the complex displays well-behaved redox processes, which may be characteristic of certain Mo–thiolate systems.
J. Hyde, L. Magin and J. Zubieta, J. Chem. Soc., Chem. Commun., 1980, 204 DOI: 10.1039/C39800000204
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