The reaction of carbon monoxide with bis(η5-cyclopentadienyl)hydridochlorozirconium(IV), cp2Zr-(H)Cl, at room temperature and atmospheric pressure, leads to a dinuclear zirconium(IV) derivative (cp2ZrCl)2CH2O; replacing CO by CO2 in this reaction results in the quantitative formation of cp2ZrCl(OMe) and (cp2ZrCl)2O.
G. Fachinetti, C. Floriani and S. Pucci, J. Chem. Soc., Chem. Commun., 1978, 269 DOI: 10.1039/C39780000269
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