Saponification of methyl N-formylcycloalkylideneglycinates (I) leads to migration of the double bond to afford N-formylcycloakl-1-enylglycines (II), which are converted into cycloalk-1-enylglycines (IV) by acid hydrolysis.
M. Suzuki, K. Nunami and N. Yoneda, J. Chem. Soc., Chem. Commun., 1978, 270 DOI: 10.1039/C39780000270
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