Wan-hong Sun,
Lan-feng Hui*,
Qian Yang and
Guo-dong Zhao
Tianjin Key Laboratory of Pulp and Paper, Tianjin University of Science & Technology, Tianjin 300457, China. E-mail: huipeak@163.com; Tel: +86-22-60602006
First published on 4th January 2021
Air filter paper with a high filtration efficiency that can remove small-size pollutant particles and toxic gases is vital for human health and the environment. We report a nanofiltration paper that is based on wood fiber filter paper with good mechanical properties and a three-dimensional network structure. The filter paper was prepared by impregnation with multi-walled carbon nanotubes (MWCNTs) and phenol-formaldehyde (PF). The results showed that MWCNTs were present on the surfaces of the fibers and between the pores, which increased the specific surface area of the fibers and enhanced the effective interception of the particles. The optimum impregnation concentration of the MWCNT was 0.1%. Compared with the cellulose fibers (CFs), the average pore diameter of the 0.1% MWCNT–CF filter paper was reduced by 8.05%, the filtration efficiency was increased by 0.64%, and the physical properties were slightly enhanced. After impregnation with PF, the mechanical properties of the air filter paper were significantly enhanced. The PF on the fiber surfaces and at the junction of the fibers covered the MWCNTs. Based on the change in the filter paper properties after impregnation, the optimal filter paper strength index and filtration performance were observed at a solid PF content of 8.4%.
Filter paper usually removes particles based on five physical effects: gravity, collision, screening, diffusion, and static electricity.6 The removal efficiency of filter paper is closely related to the relative size of the particle diameter and the paper pore size. Smaller pore sizes of the paper correspond to smaller sizes of the particles that it can intercept under the same filtration efficiency.7,8 Adjusting the structure of the filter paper to improve the air flow resistance can increase the residence time of the pollutant particles in the filter paper, resulting in a higher removal efficiency.9,10 However, the filter filtration resistance directly affects the energy consumption of the filter, such that extremely high filtration resistances are not recommended.11 The filtration efficiency has exhibited dependence on the fiber coarseness. Specifically, finer fibers have exhibited higher filtration efficiencies at a constant pressure drop.12 However, air filter paper must maintain a certain porosity to allow air flow. Nanofibers can increase the specific surface area of the filter paper to generate filter papers with small pore sizes, high filtration efficiencies, and high porosities.
Traditional air filter paper is mainly composed of micron-grade fibers with high air permeability, small airflow resistance, and a poor filtration effect for small particles, which do not meet the requirements of many modern industries for high filtration precision air filter paper. In our work, multi-walled carbon nanotube (MWCNT) air filter paper with a high filtration efficiency and antibacterial activity for extremely small particle pollutants was prepared.13 To reduce the pore size of the filter paper, MWCNTs with large aspect ratios and high specific surface areas were introduced to cellulose fiber (CF) filter paper, which has a low filtration resistance and high mechanical strength due to its porous nanofiber structure.14 The MWCNT–CF filter paper exhibited high air permeability following the incorporation of the MWCNTs. In addition, the MWCNTs exhibited a fine antibacterial ability, which is suitable for industries that require antibacterial, high-efficiency air filter paper.
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The calculation formula of the dust retention is defined as follows:
CR = Mi − Mj −M, | (3) |
Filter paper | Impregnation amount (%) |
---|---|
0.01% MWCNT–CF | 2.96 |
0.05% MWCNT–CF | 3.40 |
0.10% MWCNT–CF | 3.68 |
0.50% MWCNT–CF | 4.56 |
1.00% MWCNT–CF | 8.05 |
Fig. 1a indicates that the whiteness of the MWCNT–CF filter paper significantly decreased as the MWCNT concentration increased from 0.01% to 0.5%, which also reflected the different loading capacities of MWCNTs on the CF filter paper. Fig. 1b shows the SEM image of the 0.1% MWCNT–CF filter paper. Many small-curved MWCNTs adhered to the surfaces of the paper fibers and between the pores, reducing the pore size. The cross-section of the 0.1% MWCNT–CF filter paper (Fig. 1c) and the surface morphology of the intermediate wood fiber in the cross-section (Fig. 1d) were characterized to verify that the MWCNTs entered the deep layer of the CF filter paper during impregnation. As shown in Fig. 1d, the MWCNT content was significantly lower than that on the paper surface, and its distribution structure was also different from that on the paper surface. MWCNTs did not adhere to the surfaces of the fibers as a result of their low content in the middle of the paper. However, due to the high concentration of MWCNTs on the paper surface, it is easy to twine due the strong van der Waals forces.18,19 This phenomenon also explains the increase in the tensile index and burst index observed on the MWCNT-impregnated filter paper (Fig. 2f).
Fig. 2a shows the conductivity test results of the MWCNT–CF filter paper at different concentrations, which were based on the MWCNT conductivity.20 The conductivity of these filter papers also reflected the MWCNT content, which was consistent with the paper whiteness results. Fig. 2b shows the pore size variations of the CF filter paper at different MWCNT impregnation concentrations. The test principle of this method was based on the through-holes in the paper. The figure with the maximum aperture was almost unchanged, and the average and minimum aperture gradually decreased. Fig. 2c shows the filtration efficiency diagram of the MWCNT–CF filter paper at end pressures of 1000 and 2000 Pa. In principle, a filtration efficiency higher than 1000 Pa was caused by the presence of a filter cake formed by dust at 2000 Pa.21 However, the measurement results closer to 100% exhibited larger measurement errors. Fig. 2c shows that the efficiency of each paper sample was more than 99%. In addition, the data did not show a significant rise or fall, which was caused by the inevitable measurement errors.
Fig. 2d presents the test results for the CF filter paper with MWCNT concentrations from 0.01% to 1%, where in the air permeability decreased by 2.82%, 3.76%, 4.37%, 6.94%, and 18.98% as the resistance increased by 22.16%, 25.12%, 26.56%, 30.37%, and 43.62%, respectively. Excess MWCNT loading onto the paper blocked the filter paper pores, resulting in poor air permeability. The paper was not able to purify a large amount of air in a short time, that is, the resistance of filtering the air flow increased and affected the energy consumption of the filter paper in the working process. Fig. 2e shows the dust retention of the MWCNT–CF filter paper at end pressures of 1000 and 2000 Pa. The dust retention also significantly affected the air filter paper, which directly determined the service life of the filter paper.22 As shown in the figure, the dust retention at 2000 Pa was higher than that at 1000 Pa, which was determined by the measurement time. The increase in the MWCNT concentration on the CF filter paper resulted in dust retention decreases of 0.83%, 7.53%, 8.33%, 48.33%, and 84.17%. The SEM images showed that the MWCNT content on the surface of the filter paper was higher than that inside. When the MWCNT concentration was more than 0.5%, the MWCNTs were intensively distributed on the surface of the filter paper, thereby holding less dust and preventing the dust from entering the interior of the large dust retention space. Based on these results, we chose to proceed using 0.1% MWCNT–CF. As shown in Fig. 2f, an increase in the MWCNT concentration first caused a rapid increase and then a slow increase in the MWCNT–CF filter paper tensile index and burst index. Although the 1% MWCNT–CF exhibited the highest physical strength compared with the MWCNT loading capacity, we chose 0.5% as the best impregnation concentration for physical strength.
Filter paper | Impregnation amount (%) | Efficiency (1000 Pa, %) | Efficiency (2000 Pa, %) |
---|---|---|---|
0.00% PF–CF | 0.00 | 96.37 | 97.09 |
5.00% PF–CF | 12.95 | 99.03 | 99.12 |
6.70% PF–CF | 17.62 | 99.05 | 99.14 |
8.40% PF–CF | 22.03 | 99.12 | 99.11 |
10.00% PF–CF | 27.55 | 99.28 | 99.19 |
0.00% PF–MWCNT–CF | 1.99 | 99.79 | 99.77 |
5.00% PF–MWCNT–CF | 15.91 | 99.93 | 99.91 |
6.70% PF–MWCNT–CF | 20.85 | 99.75 | 99.89 |
8.40% PF–MWCNT–CF | 26.08 | 98.60 | 99.35 |
10.00% PF–MWCNT–CF | 30.73 | 98.23 | 99.92 |
As shown in Fig. 3c, the mean flow pore sizes and smallest pore sizes of each filter paper sample were slightly reduced. These results were due to the presence of alcohol-soluble PF on the fiber surface and at the fiber junction, and the degree of heat transfer in the fiber direction was insignificant during the drying process of the filter paper. Thus, the PF did not significantly reduce the pore size of the filter paper.
Fig. 4a shows the change of the air permeability and the resistance of the PF-impregnated CF filter paper and the 0.5% MWCNT–CF filter paper with different solid contents. As shown in the figure, the air permeability of the PF–CF filter paper was higher than that of the PF–MWCNT–CF filter paper with the same solid content, and the opposite resistance was observed. The CF filter paper air permeability decreased by 1.37%, 4.34%, 4.67%, and 6.14%, and the resistance increased by 2.55%, 4.73%, 10.38%, and 15.82%, respectively, as the PF solid content increased from 5% to 10% compared with the original paper. The air permeability of the MWCNT–CF filter paper was reduced by 3.09%, 4.32%, 5.18%, and 6.27%, and the resistance increased by 5.63%, 4.10%, 11.80%, and 15.89%, respectively, compared with the MWCNT–CF filter paper without PF impregnation. These values did not change significantly. The change in the PF solid content minimally affected the air permeability and resistance of the filter paper.
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Fig. 4 Test performance chart of the PF-impregnated filter paper. (a) Air permeability and resistance. (b) Dust retention. |
As shown in Fig. 4b, the increase in the PF solid content resulted in a slight decrease in dust retention of both filter paper samples at end pressures of 1000 and 2000 Pa. However, the dust retention of the PF–MWCNT–CF filter paper was very low due to the influence of the MWCNTs. The decrease in the dust retention was consistent with the decrease in the pore size.
Fig. 5a shows the change in the tensile index of the two filter paper samples after impregnation with PF. The tensile index of the two kinds of filter paper significantly increased after impregnation with PF. An increase in the PF solid content minimally affected the transverse tensile strength of the CF filter paper. The transverse tensile index of the MWCNT–CF filter paper did not significantly change with the increase in the PF solid content. The longitudinal tensile index of the two kinds of filter paper first increased, then decreased, and finally reached a maximum at 8.4%. This was the same trend as the burst index of the two filter paper samples shown in Fig. 5b. After the filter paper was impregnated by PF and dried in the oven, a stable three-dimensional network structure was formed. The surface layer of the fiber and the interface between the fibers were covered by PF, which generated a more stable network structure and enhanced the physical properties of the filter paper. Although the tensile and bursting strengths of the filter paper increased after impregnation with PF, the paper weight also increased, and the ratio of the two can highlight the change of the paper strength. Herein, 8.4% PF–MWCNT–CF exhibited the optimal results.
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Fig. 5 Test performance chart of the PF-impregnated filter paper. (a) Tensile index. (b) Burst index. |
The filtration performance of the MWCNT–CF filter paper impregnated with PF showed little change. The burst index of PF–MWCNT–CF filter paper increased by 110% compared with MWCNT–CF filter paper. The tensile index increased constantly, but the dust retention was too low when the PF solid content was 10%. Thus, the optimal impregnation concentration was 8.4%. At this time, the longitudinal tensile index and transverse tensile index of the filter paper increased by 77.01% and 80.41% respectively, compared with MWCNT–CF filter paper.
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