DOI:
10.1039/C7RA08227D
(Paper)
RSC Adv., 2017,
7, 42505-42512
Adsorption and separation properties of positively charged ZrO2 nanofibrous membranes fabricated by electrospinning
Received
26th July 2017
, Accepted 29th August 2017
First published on 1st September 2017
Abstract
As a new type of adsorption and separation materials, positively charged ceramics exhibit the advantages of safety and high separation efficiency. However, these materials possess low specific surface area and adsorption capacity. In this study, positively charged ZrO2 nanofibrous membranes were fabricated by electrospinning and calcination. The membranes were characterized in terms of morphology, composition, and pore structure. The adsorption and separation performance of the membranes on titan yellow solution was also investigated. Overlapping electrospun nanofibers formed nanofibrous membranes with porous structures (pore size of 0.2–1.6 μm) and a high specific surface area. Increasing the nanofiber diameter decreased the specific surface area of the nanofibrous membranes, and vacuum calcination increased their surface positive charge. The maximum flux of the positively charged ZrO2 nanofibrous membranes reached 523 L (m2 h)−1, and the interception rate for titan yellow was 99.997%. The saturated adsorption capacity of vacuum-calcined ZrO2 nanofibrous membranes increased with increasing specific surface area, and their maximum adsorption capacity reached 20.93 mg cm−3.
Introduction
In materials science, viruses and bacteria are charged colloidal particles.1 Most viruses or bacteria in nature are negatively charged.2,3 In 1991, scholars proposed the separation of viruses by using positively charged porous materials with fixed charges on the surface.4 This method utilizes not only the physical separation of pores but also the electrostatic adsorption of positive charges on the surface, and the resultant large-pore materials can absorb small-sized bacteria and viruses. Porous ceramics incorporated in positively charged materials exhibit high-temperature resistance, chemical resistance, microbial resistance, and high mechanical properties5,6 and can be recycled by high temperature and ultraviolet radiation after the separation of bacteria and viruses.7,8 Nanoporous Al2O3 coatings prepared on the surface of activated carbon particles can increase the isoelectric point of the surface and the removal efficiency of Escherichia coli MS2.9 In a previous study, positively charged ZrO2 or Y2O3 nanocoating was loaded on diatomite by impregnation and sintering;10,11 the coating showed a removal rate of 99% for E. coli MS2 but exhibited a low specific surface area (8 m2 g−1), which led to low adsorption capacity for other bacteria and viruses. Hence, micro/nanoporous ceramic membranes with high porosity, specific surface area, and adsorption capacity12,13 should be used as adsorbent materials to effectively separate and remove negatively charged viruses and bacteria.
Porous ceramic membranes with high porosity and specific surface area can be easily prepared by electrospinning.14,15 Oxide nanofibrous membranes prepared by electrospinning possess a high specific surface area of 10–100 m2 g−1.16–18 In addition, ceramic nanofibers exhibit a small diameter and can be spliced into porous membranes, with pore sizes of 0.05–2.0 μm;19 these nanofibers are used for physical separation because of their high adsorption capacity for viruses and bacteria. In this study, positively charged ZrO2 nanofibrous membranes were fabricated by electrospinning. ZrO2 was chosen on the basis of potential data for the material, which indicated that it could exhibit a positive surface charge across a wide pH range and will achieve high interception rate and adsorption capacity. The membranes obtained by vacuum calcination exhibited higher isoelectric point than those fabricated in air. The membranes were also characterized in terms of morphology and physical properties, and their adsorption and separation performance for titan yellow (mimovirus surface charge) was investigated under different environmental conditions. The fabricated positively charged ZrO2 nanofibrous membranes exhibit potential for infectious virus protection, water treatment, pharmaceutical production, and biological engineering.
Experimental
Materials and methods
Zirconium oxychloride (ZrOCl2, AR, Tianjin Guangfu Fine Chemical Research Institute, Tianjin, China) was used as Zr precursor. Absolute ethanol (AR, Anhui Ante Biochemical Co., Ltd., Suzhou, Anhui, China), N′,N-dimethylformamide (DMF, AR, Tianjin Kermel Chemical Reagent Co., Ltd., Tianjin, China), and deionized water were used as solvents. Polyvinylpyrrolidone (PVP, Mw = 1
300
000) was purchased from Alfa Aesar (Ward Hill, MA, USA) and used as spinning agent.
Solution A was prepared by mixing PVP in 15 mL of absolute ethanol under stirring for 4 h. Solution B was prepared by mixing 2 g of ZrOCl2 (2 g), 4 mL of DMF, and 1 mL of deionized water under stirring for 4 h. Solution B was gradually added to solution A, and the mixture was stirred for 2 h to obtain ZrO2 precursor solutions with PVP contents of 3, 4, 5, and 6 wt%. The precursor solutions were then placed in the micropump of an electrostatic jet apparatus (KH-08, Beijing Kangsente Co. Ltd., Beijing, China) to obtain PVP/ZrOCl2 composite nanofibers. A voltage of 18 kV was applied with a flow rate of 0.4 mL h−1. The distance from the nozzle tip to the collector was 10 cm. The temperature of the electrospinning environment was 40 °C, and the humidity was maintained at 40%. The composite nanofibers were calcined at 500–700 °C for 2 h to form ZrO2 nanofibrous membranes. The composite nanofibers were then calcined in vacuum to increase the surface isoelectric point.
Characterization
X-ray diffraction (XRD, Model 7000, Shimadzu Ltd., Japan) analysis with Cu Kα radiation (operating at 40 kV and 40 mA) was conducted to identify phases present in the ZrO2 nanofibrous membranes. The morphologies of the resulting nanofibrous membranes were characterized by scanning electron microscopy (SEM, JSM 6700, Olympus, Tokyo, Japan). The pore size of the membranes and the diameter of the nanofibers were determined through surface measurement of the SEM images with SmileView (Software, JEOL, Japan). Fifty samples were tested to determine the pore size and diameter distribution. The ZrO2 nanofibrous membranes were characterized with a model BK122T-B analyzer by N2 adsorption analysis. The surface area of the membranes was evaluated with the Brunauer–Emmett–Teller (BET) model. JS94H-type micro electrophoresis apparatus was used to test the potential of ZrO2 nanofibrous membranes and characterize their surface electrical properties. Electron binding energy of Zr 3d was also analyzed with X-ray photoelectron spectroscopy (XPS, AXIS-ULTRA DLD, Shimadzu Corporation, Tokyo, Japan) over the range of 0–1200 eV by using Al Kα radiation.
The adsorption and separation properties of the positively charged ZrO2 nanofibrous membranes were characterized using titan yellow as the simulated virus. Titan yellow is a negatively charged pigment with two negative charges in its molecules;20 this dye will be adsorbed on the surface of the positively charged material. Hence, interception rate and adsorption capacity for titan yellow can be used to evaluate the adsorption and separation properties of positively charged materials. Titan yellow solutions with different concentrations were prepared, and the absorbance standard curve was obtained using METASH UV-5100 UV visible spectrophotometer. Water flux was determined by Hydra MF/UF-type membrane flux meter. The volume of the membrane per unit area in unit time was obtained using eqn (1).
|
![image file: c7ra08227d-t1.tif](/image/article/2017/RA/c7ra08227d/c7ra08227d-t1.gif) | (1) |
where,
J is the water flux [L (m
2 h)
−1],
Q is the volume of filtered water (L),
A is the effective filtration area of membranes (m
2), and Δ
t is the test time (h). A 20 mL titan yellow solution (10 mg L
−1) was filtered using the positively charged ZrO
2 nanofibrous membranes under different pH conditions. The absorbance of the original solution and the filtered solution was determined, and interception rate was calculated using
eqn (2).
|
![image file: c7ra08227d-t2.tif](/image/article/2017/RA/c7ra08227d/c7ra08227d-t2.gif) | (2) |
where
R is the interception rate,
A1 is the absorbance of the original titan yellow solution, and
A2 is the absorbance of the filtered titan yellow solution. A 1 L titan yellow solution (10 mg L
−1) was filtered using the positively charged ZrO
2 nanofibrous membranes under different pH conditions to determine the adsorption capacity.
Results and discussion
Phase composition of ZrO2 nanofibrous membranes
Fig. 1 shows the XRD patterns of ZrO2 nanofibrous membranes before and after calcination. A broad diffraction peak appears at 2θ = 25° before the calcination of the PVP/ZrOCl2 composite nanofibers; this peak is the semi crystalline peak of PVP in the composite nanofibers. A dome-shaped diffraction peak was found at 2θ = 25–35° when the fibers were calcined at 500 °C. This finding indicates that the nanofibrous membranes remained amorphous. When calcined at 600 °C, the tetragonal phase of ZrO2 was formed, and the obtained diffraction peaks of the nanofibrous membranes are consistent with those of JCPDS 17-0923. When calcined at 700 °C, the tetragonal crystal surface (103) diffraction peak occurred at 2θ = 59.28°, and the intensity of the crystalline peak of ZrO2 increased.
![image file: c7ra08227d-f1.tif](/image/article/2017/RA/c7ra08227d/c7ra08227d-f1.gif) |
| Fig. 1 XRD patterns of ZrO2 nanofibrous membranes before and after calcinations. | |
Morphologies and physical properties of ZrO2 nanofibrous membranes
Fig. 2 shows the morphologies of ZrO2 nanofibrous membranes fabricated using precursor solutions with different PVP contents. A smooth nanofiber surface was obtained after calcination. The average diameter of the ZrO2 nanofibers increases with increasing PVP content in the precursor solutions. This result is directly related to the diameter of the composite nanofibers fabricated by electrospinning.21 Table 1 shows the viscosity, conductivity, and surface tension of the precursor solutions with different PVP contents and the average diameter of the composite nanofibers. The average diameter of the composite nanofibers increases with increasing PVP content. When the PVP content is 3 wt%, the viscosity of the precursor solution is only 245 mPa s. The viscous resistance of the precursor solution is low and insufficient to resist the stretching of the electric field force.22 The jet splits in the tensile process, resulting in fine fibers with partial linear density distribution. The conductivity of the solution is 1947 μS cm−1, which is beneficial to the stretching of the nanofiber; hence, the diameter of the composite nanofiber is small. With increasing PVP content, the viscosity of the precursor solution increases. The viscous resistance gradually increases, and the conductivity decreases, leading to increased nanofiber diameter. Fig. 3 shows the changes in the pore size formed after bonding of the nanofibers.
![image file: c7ra08227d-f2.tif](/image/article/2017/RA/c7ra08227d/c7ra08227d-f2.gif) |
| Fig. 2 Morphologies of ZrO2 nanofibrous membranes obtained using precursor solutions with different PVP contents: (a) 3 wt%, (b) 4 wt%, (c) 5 wt%, and (d) 6 wt%. | |
Table 1 Viscosity, conductivity, and surface tension of the precursor solutions with different PVP contents and average diameters of the fabricated composite nanofibers by electrospinning
PVP content (wt%) |
3 |
4 |
5 |
6 |
Viscosity (mPa s) |
245 |
335 |
507 |
628 |
Conductivity (μS cm−1) |
1947 |
1750 |
1433 |
1396 |
Surface tension (mN m−1) |
25.8 |
24.6 |
25.1 |
25.3 |
Average diameter (nm) |
185.2 |
247.3 |
331.1 |
402.5 |
![image file: c7ra08227d-f3.tif](/image/article/2017/RA/c7ra08227d/c7ra08227d-f3.gif) |
| Fig. 3 Pore size distributions of ZrO2 nanofibrous membranes obtained using precursor solutions with different PVP contents: (a) 3 wt%, (b) 4 wt%, (c) 5 wt%, and (d) 6 wt%. The inset images show the nanofiber diameter distributions. | |
The pore size of the nanofibrous membranes affects the flux and is crucial to their adsorption and separation properties. With increasing PVP content, the pore size distribution of ZrO2 fibers is uneven, and the average pore size decreases slightly. This finding could be due to increase in the diameter of ZrO2 nanofibers (shown in insert images of Fig. 3) as the PVP content increases. Overlapped nanofibers are dense and decrease the pore size between nanofibers. Moreover, the distribution of ZrO2 nanofibers fabricated by the precursor solution with high PVP content is uneven, and some nanofibers have large diameter, resulting in reduced pore size between nanofibers. The pore sizes of the ZrO2 nanofibrous membranes are between 0.2 and 1.6 μm, which conform to the pore size range of the microfiltration membranes.
The specific surface area of ZrO2 nanofibrous membranes affects their adsorption capacity and is related to the average diameter of ZrO2 nanofibers. Fig. 4 shows the BET surface curves of ZrO2 nanofibrous membranes with different average diameters of nanofibers. By determining the equilibrium adsorption capacity, the specific surface area of the sample was calculated using the theoretical model. The equilibrium adsorption capacity of nitrogen molecules on the sample surface was measured, and the monolayer saturated adsorption capacity was calculated by the BET theoretical model to determine the number of molecules. The equivalent maximum cross-sectional area of the nitrogen molecule was calculated using the surface-closed six-party model. The specific surface area of the sample was then obtained using eqn (3).
|
![image file: c7ra08227d-t3.tif](/image/article/2017/RA/c7ra08227d/c7ra08227d-t3.gif) | (3) |
where
Sg is the specific surface area,
Vm is the single-layer saturated adsorption capacity of nitrogen molecules in standard conditions,
N is the Fugadero constant (6.02 × 10
23),
Am is the equivalent maximum cross-sectional area of molecular nitrogen (theories value
Am = 0.162 nm), and
W is the quality of the sample. The BET equation is as follows.
|
![image file: c7ra08227d-t4.tif](/image/article/2017/RA/c7ra08227d/c7ra08227d-t4.gif) | (4) |
where
P is the nitrogen pressure,
P0 is the saturated vapor pressure of the sample,
V is the actual adsorption amount of the sample,
Vm is the single-layer saturated adsorption capacity of nitrogen molecules under standard conditions, and
C is the parameter related to the adsorption capacity of the sample. The specific surface area of the ZrO
2 nanofibrous membranes decreases from 17.67 m
2 g
−1 to 14.65 m
2 g
−1 with increasing nanofiber diameter. When the average diameter of the ZrO
2 nanofibers is 142.5 nm, the maximum specific surface area of the membrane is 17.67 m
2 g
−1. The specific surface area of the electrospun ZrO
2 nanofibrous membranes is higher by more than twice than that of conventional porous ceramic filter (8 m
2 g
−1).
11 This finding is explained by the low porosity and surface area of traditional porous ceramic filters. The electrospun nanofibrous membranes exhibit the advantages of high specific surface area and porosity.
![image file: c7ra08227d-f4.tif](/image/article/2017/RA/c7ra08227d/c7ra08227d-f4.gif) |
| Fig. 4 BET surface curves of ZrO2 nanofibrous membranes with different average diameters of nanofibers: (a) 142.5 nm, (b) 165.6 nm, (c) 206.3 nm, and (d) 279.1 nm. | |
Positively charged properties of ZrO2 nanofibrous membranes
The isoelectric point of metal oxide ceramics is used extensively in materials science in various aqueous processing steps. In the absence of chemisorbed or physisorbed species, particle surfaces in aqueous suspensions are generally assumed to be covered with surface hydroxyl species.23 At pH values above the isoelectric point, the predominate surface species is M–O−, whereas at pH values below the isoelectric point, M–OH2+ species predominate. Fig. 5 shows the zeta potential of ZrO2 nanofibrous membranes at different pH values. The isoelectric point of ZrO2 nanofibers obtained by atmospheric calcination is 4.3, whereas the isoelectric point is 4.8 when calcined in vacuum. Vacuum calcination can increase the isoelectric point of ZrO2 nanofibrous membranes, which is related to the crystallization process of ZrO2. The ratio of Zr atoms to O atoms is 1
:
1 in ZrOCl2, and its decomposition process requires O2 to participate. During vacuum calcination, oxygen vacancies existed in the resulting ZrO2, which makes the isoelectric point move to the right. In the pH value solution below the isoelectric point, the surface of ZrO2 nanofibers is covered with a positively charged group, and the zeta potential is positively charged. At low pH levels, the positive charge is high. When the pH value is 3, the zeta potential of the vacuum-calcined ZrO2 nanofibrous membranes reaches 18.39 mV. The binding energy of Zr in ZrO2 nanofibrous membranes calcined in different atmospheres was characterized (Fig. 6). The peaks of Zr 3d of vacuum-calcined ZrO2 nanofibrous membranes shifted to the right compared with the atmospheric calcination; this finding indicates that the binding energy of Zr decreases. The decrease in binding energy generally indicates that the electron cloud density around the atom increases, and the valence state of oxide decreases.24 This finding indirectly indicates that the number of oxygen vacancies in the vacuum-calcined ZrO2 nanofibrous membranes is higher than that in the atmospheric calcined membranes. The more the oxygen vacancies, the higher zeta-positive potential of membranes and the higher the positive charge will be.
![image file: c7ra08227d-f5.tif](/image/article/2017/RA/c7ra08227d/c7ra08227d-f5.gif) |
| Fig. 5 Zeta potentials of ZrO2 nanofibrous membranes at different pH values. | |
![image file: c7ra08227d-f6.tif](/image/article/2017/RA/c7ra08227d/c7ra08227d-f6.gif) |
| Fig. 6 XPS spectra of Zr 3d in ZrO2 nanofibrous membranes obtained by calcination in different atmospheres. | |
Membrane flux of positively charged ZrO2 nanofibrous membranes
Water flux can influence the filtration efficiency of nanofibrous membranes when used for adsorption separation. Large water flux requires short time to filter the same volume of solutions. Fig. 7 shows the water flux of ZrO2 nanofibrous membranes with different average pore sizes. The effective filtration area of nanofibrous membranes is 12.56 cm2, the membrane thickness is 1 mm, and the operation pressure is 1 Pa. The water fluxes increase with the increase of average pore size of ZrO2 nanofibrous membranes, which were all above 500 L (m2 h)−1. When the average pore size of ZrO2 nanofibrous membranes is 702.2 nm, the maximum water flux can reach 523 L (m2 h)−1. The water flux is five times higher than the traditional ceramic microporous filter membrane and the operation pressure is low.25 The water flux of a filter membrane is mainly related to thickness, osmotic pressure, pore size, and porosity. Under the premise of certain membrane thickness and operating pressure, the larger the pore size, the smaller the permeate resistance and the easier the penetration of water molecules will be. Therefore, the water flux is positively related to the pore size of nanofibrous membranes.
![image file: c7ra08227d-f7.tif](/image/article/2017/RA/c7ra08227d/c7ra08227d-f7.gif) |
| Fig. 7 Water flux of ZrO2 nanofibrous membranes with different average pore sizes. | |
Adsorption and separation properties of positively charged ZrO2 nanofibrous membranes
Fig. 8 shows interception rates of ZrO2 nanofibrous membranes at different pH values. titan yellow interception rate of air-calcined ZrO2 nanofibrous membranes remained above 99.99% in the solution with pH = 3.5, and the maximum interception rate was 99.996% in pH = 3 solution. The interception rate drops rapidly in the solution with pH > 4 and then tends to be smooth; the interception rate is only 0.08% in the solution with pH > 6. The interception rate of vacuum-calcined nanofibrous membranes for titan yellow is 99.997% in the solution with pH = 3–4. The interception rate of ZrO2 nanofibrous membranes is closely related to the electrical properties of the nanofiber surface. The interception rate of vacuum-calcined nanofibrous membranes is similar to that calcined in the air, but the pH range for removing titan yellow is widened slightly due to the increase of the isoelectric point. The surface of ZrO2 nanofibers carries positive charges in the solution of pH < IEP; titan yellow molecules with negative charge were adsorbed, and the interception rate is high. By contrast, the interception rate is low in pH > IEP solutions due to electrostatic repulsion.
![image file: c7ra08227d-f8.tif](/image/article/2017/RA/c7ra08227d/c7ra08227d-f8.gif) |
| Fig. 8 Interception rates of ZrO2 nanofibrous membranes at different pH values. | |
Fig. 9 shows adsorption capacities of vacuum-calcined ZrO2 nanofibrous membranes with different specific surface area at different pH values. The adsorption capacity of vacuum-calcined ZrO2 nanofibrous membranes reached 20.93 mg cm−3 when its specific surface area was 17.67 m2 g−1 in the solution with pH = 3–3.5. The saturated adsorption capacity decreased rapidly and is only about 0.01 mg cm−3 in the solution with pH > 6. The saturation adsorption capacity of ZrO2 nanofibrous membranes for titan yellow is related to the isoelectric point and the specific surface area.26 In generally, the specific surface area of nanofibrous membranes is mainly affected by the nanofiber diameter, and reducing the nanofiber diameter can improve its specific surface area. However, pore sizes formed by nanofibers bonding decrease when the diameter decrease excessively, which may affect the water flux of membranes. ZrO2 nanofibrous membranes with high isoelectric point and high specific surface area have high adsorption capacity, which can prolong the service life of the filter.
![image file: c7ra08227d-f9.tif](/image/article/2017/RA/c7ra08227d/c7ra08227d-f9.gif) |
| Fig. 9 Adsorption capacities of ZrO2 nanofibrous membranes calcined in vacuum with different specific surface areas at different pH values. | |
Conclusions
Positively charged ZrO2 nanofibrous membranes were fabricated by electrospinning; the highest specific surface area of the membranes is 17.67 m2 g−1. After vacuum calcination, the oxygen vacancies on the surface of nanofibers increased, and the isoelectric point of nanofibrous membranes increased from 4.3 to 4.7. The maximum water flux of the positively charged ZrO2 nanofibrous membranes is 523 L (m2 h)−1 with an effective filtration area of 12.56 cm2, a thickness of 1 mm, and an operating pressure of 1 Pa. The interception rate of vacuum-calcined nanofibrous membranes for titan yellow is 99.997% in the solution with pH = 3–4, and its maximum saturated adsorption capacity reached 20.93 mg cm−3. ZrO2 nanofibrous membranes exhibit improved adsorption and separation performance compared with the traditional ceramic porous filter. These membranes have a wide application prospect in infectious virus protection, water treatment, pharmaceutical production, and biological engineering. However, in vacuum calcination, the spinning agent PVP cannot be completely decomposed and there may be residuals, which have an impact on the positively charge membrane. In addition, the isoelectric point of ZrO2 nanofibrous membranes have to be improved further for treatment of neutral or alkaline sewage, which is the main research direction in the future.
Conflicts of interest
There are no conflicts to declare.
Acknowledgements
The authors would like to acknowledge the support from the National Natural Science Foundation of China (No. 51572217 and 51672211), the China Postdoctoral Science Foundation (No. 2015M582689) and the Postdoctoral Science Foundation of Shaanxi Province (No. 2016BSHEDZZ03).
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