Issue 97, 2015
From the journal:

RSC Advances

Selective synthesis of 2,5-disubstituted furan-3-carboxylates and the isomeric 2,4-disubstituted furan-3-carboxylates†

Panpan Chen,a   Yinggao Meng,a   Qinghua Yang,b   Jie Wu,*a   Yuanyuan Xiao,a   Dhilli Rao Gorja,c   Chuanjun Song*a  and  Junbiao Chang*a  

* Corresponding authors

a College of Chemistry and Molecular Engineering, Zhengzhou University, 100 Science Avenue, Zhengzhou 450001, P. R. China
E-mail: changjunbiao@zzu.edu.cn, chjsong@zzu.edu.cn, wujie@zzu.edu.cn

b School of Pharmaceutical Sciences, Zhengzhou University, 100 Science Avenue, Zhengzhou 450001, P. R. China

c China-US (Henan) Hormel Cancer Institute, 127 Dongming Road, Zhengzhou 450003, P. R. China

Abstract

An unprecedented Ag2CO3 and DBU mediated cyclization of 3-substituted 2-(2-bromoallyl)-3-oxo-1-carboxylates leading to the formation of 2,5-disubstituted furan-3-carboxylates has been reported. In the absence of a silver salt, the isomeric 2,4-disubstituted furan-3-carboxylates are obtained.

Graphical abstract: Selective synthesis of 2,5-disubstituted furan-3-carboxylates and the isomeric 2,4-disubstituted furan-3-carboxylates

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C5RA14273C
Article type
Paper
Submitted
20 Jul 2015
Accepted
15 Sep 2015
First published
16 Sep 2015

RSC Adv., 2015,5, 79906-79914

Permissions

Request permissions

Selective synthesis of 2,5-disubstituted furan-3-carboxylates and the isomeric 2,4-disubstituted furan-3-carboxylates

P. Chen, Y. Meng, Q. Yang, J. Wu, Y. Xiao, D. R. Gorja, C. Song and J. Chang, RSC Adv., 2015, 5, 79906 DOI: 10.1039/C5RA14273C

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements