Issue 21, 1994

Stacked amido macrocyclic complexes: synthesis and single crystal X-ray structure of Na[Cu(L)(NCMe)](BF4)2(NO3)[L = 1-formyl-4,7-bis(2-hydroxy-2-methylpropyl)-1,4,7-triazacyclononane]

Abstract

The synthesis of bi-functional derivatives of [9]aneN3 is described; the structure of Na[Cu(L)(NCMe)](BF4)2(NO3) shows a central [Na(BF4)2] core with the O-donor of the amide moiety of successive [Cu(L)(NCMe)]2+ cations bound Na+ to give a stacked structure.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1994, 2467-2469

Stacked amido macrocyclic complexes: synthesis and single crystal X-ray structure of Na[Cu(L)(NCMe)](BF4)2(NO3)[L = 1-formyl-4,7-bis(2-hydroxy-2-methylpropyl)-1,4,7-triazacyclononane]

A. J. Blake, I. A. Fallis, R. O. Gould, S. Parsons, S. A. Ross and M. Schröder, J. Chem. Soc., Chem. Commun., 1994, 2467 DOI: 10.1039/C39940002467

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