Direct irradiation of α,β-unsaturated γ,δ-epoxy nitriles (e.g.1) and tertiary amines gives rise to a novel 1:1 α-addition and subsequent retro-Michael reaction leading to α-alkylidenenitriles (e.g.2).
K. Ishii, M. Kotera and M. Sakamoto, J. Chem. Soc., Chem. Commun., 1994, 2465 DOI: 10.1039/C39940002465
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