Thermal decompostion of 1-methyl-1,2,3-benzotriazian-4(1H)-one (1) above 120°C gave rise to 1-methylbenzazetinone (2), which was trapped in solid argon at 15 K; near-UV irradiation of (2) converted it partially into its iminoketene isomer (3), and the reverse conversion of (3) into (2) was effected with longer wavelength irradiation.
I. R. Dunkin, M. A. Lynch, R. Withnall, A. J. Boulton and N. Henderson, J. Chem. Soc., Chem. Commun., 1989, 1777 DOI: 10.1039/C39890001777
To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.
If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.
If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.
Read more about how to correctly acknowledge RSC content.
Please wait while we load your content...