The chirality of the sulphinate sulphur atoms has been transferred to the carbon centres in chiral allylic sulphinate–sulphone rearrangements, followed by palladium-catalysed intramolecular ene reactions of the chiral allylic sulphones obtained, with high stereospecificity.
K. Hiroi and Y. Kurihara, J. Chem. Soc., Chem. Commun., 1989, 1778 DOI: 10.1039/C39890001778
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