X-Ray studies of the thermodynamically less stable (in solution) diastereoisomeric rotational isomer of 3-(2-bromophenyl)-5-methyl-2-thiohydantion (II) show that the bromine atom is transoid to the 5-methyl group.
P. H. Bird, L. D. Colebrook, A. R. Fraser and H. G. Giles, J. Chem. Soc., Chem. Commun., 1974, 225 DOI: 10.1039/C39740000225
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