A new synthetic route to metal trithiophosphonates: Syntheses and structures of [(C6H11)PS3Li2·THF·TMEDA]2 and [(C6H11)PS3Mg·2THF]2

Jens K. Bjernemose; Robert P. Davies; Andrew P. S. Jurd; M. Giovanna Martinelli; Paul R. Raithby; Andrew J. P. White

doi:10.1039/B412488J

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A new synthetic route to metal trithiophosphonates: Syntheses and structures of [(C₆H₁₁)PS₃Li₂·THF·TMEDA]₂ and [(C₆H₁₁)PS₃Mg·2THF]₂†

Jens K. Bjernemose,^b Robert P. Davies,*^a Andrew P. S. Jurd,^a M. Giovanna Martinelli,^a Paul R. Raithby^b and Andrew J. P. White^a

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* Corresponding authors

^a Department of Chemistry, Imperial College London, South Kensington, London, UK
E-mail: r.davies@imperial.ac.uk

^b Department of Chemistry, University of Bath, Claverton Down, Bath, UK

Abstract

A new synthesis for trithiophosphonates from primary phosphines, nBuLi (or nBu₂Mg) and elemental sulfur is presented and its mechanism investigated; the lithium and magnesium salts of cyclohexyltrithiophosphonate have been fully characterised to reveal dimers in the solid state in which all three of the trithiophosphonate sulfurs are involved in metal bonding.

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Article information

DOI: https://doi.org/10.1039/B412488J
Article type: Communication
Submitted: 13 Aug 2004
Accepted: 08 Sep 2004
First published: 20 Sep 2004

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Dalton Trans., 2004, 3169-3170

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A new synthetic route to metal trithiophosphonates: Syntheses and structures of [(C₆H₁₁)PS₃Li₂·THF·TMEDA]₂ and [(C₆H₁₁)PS₃Mg·2THF]₂

J. K. Bjernemose, R. P. Davies, A. P. S. Jurd, M. G. Martinelli, P. R. Raithby and A. J. P. White, Dalton Trans., 2004, 3169 DOI: 10.1039/B412488J

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Dalton Transactions