Issue 20, 2004
From the journal:

Dalton Transactions

Solution- and solid-state characterisation of a configurationally-stable β-diketiminato-supported calcium primary amide†

Anthony G. Avent,b   Mark R. Crimmin,a   Michael S. Hill*a  and  Peter B. Hitchcockb  

* Corresponding authors

a Department of Chemistry, Imperial College London, Exhibition Road, South Kensington, London, UK
E-mail: mike.hill@imperial.ac.uk
Fax: +44 (0)20 7594 5804
Tel: +44 (0)207 594 5709

b The Chemistry Laboratory, University of Sussex, Falmer, Brighton, East Sussex, UK

Abstract

‘Selective’ protonolysis of the β-diketiminato calcium derivative [Ca{(NDippCMe)2CH}{N(SiMe3)2}(THF)] (Dipp = C6H3iPr2-2,6) with H2N(CH2)2OCH3 produced the dimeric species [Ca{(NDippCMe)2CH}{μ-NH(CH2)2OMe}]2, which has been fully characterised in solution and in the solid state.

Graphical abstract: Solution- and solid-state characterisation of a configurationally-stable β-diketiminato-supported calcium primary amide

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Article information

DOI
https://doi.org/10.1039/B412060D
Article type
Communication
Submitted
05 Aug 2004
Accepted
13 Sep 2004
First published
23 Sep 2004

Dalton Trans., 2004, 3166-3168

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Solution- and solid-state characterisation of a configurationally-stable β-diketiminato-supported calcium primary amide

A. G. Avent, M. R. Crimmin, M. S. Hill and P. B. Hitchcock, Dalton Trans., 2004, 3166 DOI: 10.1039/B412060D

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