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Issue 20, 2004
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The reaction of RhCp*(CH3)2 (L) (L = pyridine, dmso) with GaCp* and AlCp*: A new type of carbon–carbon bond activation reaction

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Abstract

Reaction of RhCp*(L)(CH3)2 (L = pyridine, dmso) with equimolar amounts of GaCp* at 60 °C quantitatively leads to the zwitterionic species [Cp*Rh(CpMe4GaMe3)]. [Cp*Rh(CH3)2(GaCp*)] could be isolated and identified as an intermediate in this reaction.

Graphical abstract: The reaction of RhCp*(CH3)2 (L) (L = pyridine, dmso) with GaCp* and AlCp*: A new type of carbon–carbon bond activation reaction

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Publication details

The article was received on 02 Jul 2004, accepted on 19 Aug 2004 and first published on 31 Aug 2004


Article type: Communication
DOI: 10.1039/B410077H
Citation: Dalton Trans., 2004,0, 3171-3172
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    The reaction of RhCp*(CH3)2 (L) (L = pyridine, dmso) with GaCp* and AlCp*: A new type of carbon–carbon bond activation reaction

    T. Cadenbach, C. Gemel, R. Schmid, S. Block and R. A. Fischer, Dalton Trans., 2004, 0, 3171
    DOI: 10.1039/B410077H

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