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Issue 45, 2020
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Remarkably enhanced proton conduction of {NBu2(CH2COOH)2}[MnCr(ox)3] by multiplication of carboxyl carrier in the cation

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Abstract

The proton conduction of {NBu2(CH2COOH)2}[MnCr(ox)3] (dic-MnCr) is studied in comparison with its analogous {NBu3(CH2COOH)}[MnCr(ox)3] (moc-MnCr). The proton conductivity is enhanced remarkably by the multiplication of the carboxyl carrier in the cation, from 5.2 × 10−7 S cm−1 at 90% RH (25 °C) in moc-MnCr to 1.8 × 10−3 S cm−1 at 95% RH (25 °C) in dic-MnCr.

Graphical abstract: Remarkably enhanced proton conduction of {NBu2(CH2COOH)2}[MnCr(ox)3] by multiplication of carboxyl carrier in the cation

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Supplementary files

Article information


Submitted
25 Mar 2020
Accepted
24 Apr 2020
First published
27 Apr 2020

Chem. Commun., 2020,56, 6138-6140
Article type
Communication

Remarkably enhanced proton conduction of {NBu2(CH2COOH)2}[MnCr(ox)3] by multiplication of carboxyl carrier in the cation

H. Ōkawa, K. Otsubo, Y. Yoshida and H. Kitagawa, Chem. Commun., 2020, 56, 6138
DOI: 10.1039/D0CC02192J

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