Issue 88, 2013
From the journal:

Chemical Communications

Synthesis of a phosphine imide bearing a hydrosilane moiety, and its water-driven reduction to a phosphine†‡

Naokazu Kano,*a   Kazuhide Yanaizumi,a   Xiangtai Meng,a   Nizam Havarea  and  Takayuki Kawashima§*a  

* Corresponding authors

a Department of Chemistry, Graduate School of Science, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-0033, Japan
E-mail: kano@chem.s.u-tokyo.ac.jp
Tel: +81 3 5841 4338

Abstract

Organosilanes bearing a phosphine imide moiety were synthesized and crystallographically characterized. Reaction of the pentacoordinated hydrodiphenylsilyl derivative with water gave [2-(diphenylphosphino)phenyl]diphenylsilanol accompanied by both reduction of the phosphine imide moiety and hydrolytic oxidation of the Si–H moiety.

Graphical abstract: Synthesis of a phosphine imide bearing a hydrosilane moiety, and its water-driven reduction to a phosphine

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Article information

DOI
https://doi.org/10.1039/C3CC43955K
Article type
Communication
Submitted
26 May 2013
Accepted
13 Jun 2013
First published
28 Jun 2013
This article is Open Access
Creative Commons BY license

Chem. Commun., 2013,49, 10373-10375

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Synthesis of a phosphine imide bearing a hydrosilane moiety, and its water-driven reduction to a phosphine

N. Kano, K. Yanaizumi, X. Meng, N. Havare and T. Kawashima, Chem. Commun., 2013, 49, 10373 DOI: 10.1039/C3CC43955K

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