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Issue 16, 2013
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A face-capped [Fe4L4]8+ spin crossover tetrahedral cage

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Abstract

Reported here is a face-capped Fe(II) molecular tetrahedron, [Fe4L4](BF4)8, 1. Single crystal X-ray diffraction at 153 and 293 K suggest spin crossover (SCO) and variable temperature magnetic susceptibility measurements confirm 1 displays thermally driven SCO behaviour in the solid state and in dilute acetone solution centred around 284–288 K.

Graphical abstract: A face-capped [Fe4L4]8+ spin crossover tetrahedral cage

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Supplementary files

Publication details

The article was received on 26 Oct 2012, accepted on 08 Jan 2013 and first published on 08 Jan 2013


Article type: Communication
DOI: 10.1039/C3CC00012E
Chem. Commun., 2013,49, 1597-1599
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    A face-capped [Fe4L4]8+ spin crossover tetrahedral cage

    A. Ferguson, M. A. Squire, D. Siretanu, D. Mitcov, C. Mathonière, R. Clérac and P. E. Kruger, Chem. Commun., 2013, 49, 1597
    DOI: 10.1039/C3CC00012E

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