Borane-catalyzed arylation of aryldiazoacetates with N,N-dialkylanilines

Cheng-Yu Chen; Jing-Hao Zhao; Li-Xue Xiong; Feiyi Wang; Guichun Yang; Chao Ma

doi:10.1039/D2OB00447J

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Borane-catalyzed arylation of aryldiazoacetates with N,N-dialkylanilines†

Cheng-Yu Chen,^a Jing-Hao Zhao,^a Li-Xue Xiong,^a Feiyi Wang,

^a Guichun Yang^a and Chao Ma

*^a

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* Corresponding authors

^a Hubei Collaborative Innovation Centre for Advanced Organic Chemical Materials, College of Chemistry and Chemical Engineering, Ministry of Education Key Laboratory for the Synthesis and Application of Organic Functional Molecules, Hubei University, Wuhan, P. R. China
E-mail: machao@hubu.edu.cn

Abstract

A selective arylation of donor–acceptor diazo compounds with aniline derivatives catalyzed by Lewis acidic boranes is developed. This simple reaction protocol provides an efficient method for the synthesis of diarylacetates under metal-free conditions.

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Article information

DOI: https://doi.org/10.1039/D2OB00447J
Article type: Communication
Submitted: 05 Mar 2022
Accepted: 05 May 2022
First published: 06 May 2022

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Org. Biomol. Chem., 2022,20, 4101-4104

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Borane-catalyzed arylation of aryldiazoacetates with N,N-dialkylanilines

C. Chen, J. Zhao, L. Xiong, F. Wang, G. Yang and C. Ma, Org. Biomol. Chem., 2022, 20, 4101 DOI: 10.1039/D2OB00447J

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Organic & Biomolecular Chemistry

Borane-catalyzed arylation of aryldiazoacetates with N,N-dialkylanilines†

Abstract

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Borane-catalyzed arylation of aryldiazoacetates with N,N-dialkylanilines

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