Issue 63, 2022
From the journal:

Chemical Communications

Ambient synthesis of metal–covalent organic frameworks with Fe-iminopyridine linkages†

Tiantian Feng,ab   Bing Sun, ORCID logo *a   Qing Hao,b   Jing Li,c   Ying Xu,b   Hong Shang ORCID logo a  and  Dong Wang ORCID logo *b  

* Corresponding authors

a School of Science, China University of Geosciences (Beijing), Beijing 100083, P. R. China
E-mail: sunbing@cugb.edu.cn

b Key Laboratory of Molecular Nanostructure and Nanotechnology, Institute of Chemistry, Chinese Academy of Sciences and Beijing National Laboratory for Molecular Sciences, Beijing 100190, P. R. China
E-mail: wangd@iccas.ac.cn

c Key Laboratory of Bio-inspired Smart Interfacial Science and Technology of Ministry of Education, School of Chemistry, Beihang University, Beijing 100191, P. R. China

Abstract

Highly crystalline Fe-COFs were constructed from the building blocks carrying pyridyl-aldehyde and triamine moieties in the presence of Fe(OTf)2 and acetic acid under ambient conditions via a subcomponent assembly strategy. The spectral results prove the coordination of atomically distributed Fe(II) ions with the nitrogen species of covalently formed iminopyridine linkages.

Graphical abstract: Ambient synthesis of metal–covalent organic frameworks with Fe-iminopyridine linkages

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Article information

DOI
https://doi.org/10.1039/D2CC03148E
Article type
Communication
Submitted
03 Jun 2022
Accepted
08 Jul 2022
First published
08 Jul 2022

Chem. Commun., 2022,58, 8830-8833

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Ambient synthesis of metal–covalent organic frameworks with Fe-iminopyridine linkages

T. Feng, B. Sun, Q. Hao, J. Li, Y. Xu, H. Shang and D. Wang, Chem. Commun., 2022, 58, 8830 DOI: 10.1039/D2CC03148E

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