Enhanced cooperativity leading to high catalytic activity and stereoselectivity has been achieved through a complex network of simple species interacting reversibly. This novel dynamic catalytic system relies on bipyridine-based organocatalytic ligands and zinc(II) as the template. It demonstrates the effectiveness of dealing with mixtures rather than single species in asymmetric catalysis.
A. Serra-Pont, I. Alfonso, J. Solà and C. Jimeno, Chem. Commun., 2019, 55, 7970 DOI: 10.1039/C9CC03958A
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