π Complexes of P^P and P^N chelated gold(I)

Miquel Navarro; Alberto Toledo; Maximilian Joost; Abderrahmane Amgoune; Sonia Mallet-Ladeira; Didier Bourissou

doi:10.1039/C9CC04266K

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π Complexes of P^P and P^N chelated gold(i)†

Miquel Navarro,

^a Alberto Toledo,^a Maximilian Joost,^a Abderrahmane Amgoune,

^a Sonia Mallet-Ladeira^b and Didier Bourissou

*^a

Author affiliations

* Corresponding authors

^a Laboratoire Hétérochimie Fondamentale et Appliquée (UMR 5069), Université de Toulouse, CNRS, 118 Route de Narbonne, 31062 Toulouse cedex 9, France
E-mail: dbouriss@chimie.ups-tlse.fr

^b Institut de Chimie de Toulouse (FR 2599), Université de Toulouse, CNRS, 118 route de Narbonne, 31062 Toulouse cedex 9, France

Abstract

Tricoordinate gold(I) π-complexes containing P-based chelating ligands (P^P and P^N) were prepared. The structure of the gold(I) styrene complexes has been analysed in detail based on NMR and XRD data. The P^N complex is a competent catalyst for indole alkylation. The reaction proceeds with complete C3 and Markovnikov selectivity.

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DOI: https://doi.org/10.1039/C9CC04266K
Article type: Communication
Submitted: 03 Jun 2019
Accepted: 13 Jun 2019
First published: 13 Jun 2019

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Chem. Commun., 2019,55, 7974-7977

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π Complexes of P^P and P^N chelated gold(I)

M. Navarro, A. Toledo, M. Joost, A. Amgoune, S. Mallet-Ladeira and D. Bourissou, Chem. Commun., 2019, 55, 7974 DOI: 10.1039/C9CC04266K

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Chemical Communications

π Complexes of P^P and P^N chelated gold(i)†

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π Complexes of P^P and P^N chelated gold(I)

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